sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

266981

Sigma-Aldrich

Nickel, powder, <50 μm, 99.7% trace metals basis

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

GF16508246

Nickel, foil, 10mm disks, thickness 0.0125mm, annealed, 99%

GF81039438

Nickel, foil, 50x50mm, thickness 0.5mm, as rolled, 99.99+%

GF95071103

Nickel, tube, 500mm, outside diameter 2.8mm, inside diameter 1.8mm, wall thickness 0.5mm, hard, 99.5%

GF49268526

Nickel, tube, 5mm, outside diameter 0.8mm, inside diameter 0.5mm, wall thickness 0.15mm, hard, 99.5%

GF19402062

Nickel, wire reel, 10m, diameter 0.25mm, annealed, 99%

GF55000628

Nickel, foil, 0.5m coil, thickness 0.075mm, as rolled, 99.98%

GF09874424

Nickel, wire reel, 10m, diameter 0.25mm, hard, 99.98%

GF56798847

Nickel, foil, 4mm disks, thickness 0.02mm, 99.9%

GF56028720

Nickel, foil, 0.5m coil, thickness 0.038mm, 99.9%

GF60017510

Nickel, foil, 0.2m coil, thickness 0.004mm, hard, 99%

GF93488596

Nickel, foil, 10mm disks, thickness 0.03mm, 99.9%

GF20430931

Nickel, rod, 1000mm, diameter 2.0mm, annealed, 99%

GF43379253

Nickel, foil, 25x25mm, thickness 0.30mm, as rolled, 99.98%

GF80763554

Nickel, foil, 50x50mm, thickness 0.5mm, annealed, 99.98%

GF34840885

Nickel, tube, 500mm, outside diameter 8.4mm, inside diameter 8.15mm, wall thickness 0.125mm, hard, 99.5%

GF88624132

Nickel, foil, 2m coil, thickness 0.075mm, as rolled, 99.98%

GF51837093

Nickel, foil, 50x50mm, thickness 1.0mm, annealed, 99%

GF46748144

Nickel, wire reel, 10m, diameter 2.0mm, hard, 99.98%

GF02127068

Nickel, foil, 10mm disks, thickness 0.0075mm, 99.9%

GF97256953

Nickel, wire reel, 1m, diameter 0.25mm, as drawn, 99.99+%

GF54176812

Nickel, wire reel, 10m, diameter 0.4mm, as drawn, 99%

GF46693109

Nickel, foil, 0.5m coil, thickness 0.0075mm, 99.95%

GF64926153

Nickel, foil, 10mm disks, thickness 0.05mm, 99.9%

GF35123486

Nickel, foil, 150x150mm, thickness 0.20mm, annealed, 99%