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Merck

HPLC Analysis of Spice Cannabinoids on Ascentisยฎ Express F5

HPLC Analysis of Spice Cannabinoids on Ascentis® Express F5 application for HPLC

Materials

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Ascentisยฎ Express F5, 2.7 ฮผm HPLC Column

2.7 μm particle size, L ร— I.D. 10 cm ร— 2.1 mm

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Spice Cannabinoid Mix solution

100 ฮผg/mL each component in acetonitrile, ampule of 1.0 mL, certified reference material, Cerilliantยฎ

HU-210 solution

100 ฮผg/mL in methanol, ampule of 1 mL, (Spice Cannabinoid), certified reference material, Cerilliantยฎ

JWH-018 solution

100 ฮผg/mL in methanol, ampule of 1 mL, certified reference material, Cerilliantยฎ

JWH-073 solution

100 ฮผg/mL in acetonitrile, ampule of 1 mL, certified reference material, Cerilliantยฎ

JWH-073 N-(3-hydroxybutyl) metabolite solution

100 ฮผg/mL in methanol, ampule of 1 mL, certified reference material, Cerilliantยฎ

CONDITIONS

column

Ascentis Express F5, 10 cm x 2.1 mm I.D., 2.7 μm particles (53569-U)

mobile phase

[A] 50 mM ammonium formate; [B] water; [C] acetonitrile; (10:35:55, A:B:C)

flow rate

0.6 mL/min

pressure

4075 psi (281 bar)

column temp.

30 ยฐC

detector

UV, 200 nm

injection

3 μL

sample

100 μg/mL in 45:55 water:acetonitrile

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Synthetic cannabinoids (e.g. "Spice") are a type of designer drug that provide a cannabis-type high. New synthetic cannabinoids are continually being introduced as suppliers tweak the molecular structures. The ability to rapidly and reliably identify the continually changing population of these compounds is a significant analytical challenge facing forensic chemists. A rapid separation of eight of these compounds on Ascentis Express F5 column is shown here. Cerilliant CRMs provided reliable identification and quantification.

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Ascentis is a registered trademark of Merck KGaA, Darmstadt, Germany