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Merck

HPLC Analysis of Active Cannabinoid Compounds in Gummy Bear Candy on Ascentisยฎ Express Biphenyl with UV Detection after Extraction

HPLC Analysis of Active Cannabinoid Compounds in Gummy Bear Candy on Ascentis® Express Biphenyl with UV Detection after Extraction application for HPLC

Materials

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Ascentisยฎ Express Biphenyl Guard Column

pkg of 3 ea, 2.7 μm particle size, L ร— I.D. 0.5 cm ร— 2.1 mm

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Supelโ„ข QuE

Empty Centrifuge Tube with Lid, centrifuge tube volume 50 mL, pk of 50, suitable for EN 15662:2008 per BS

Certified Vial Kit, Low Adsorption (LA), 2 mL, pk of 100

volume 2 mL, amber glass vial (with marking spot), natural PTFE/silicone septa, thread for 9 mm

QuEChERS Shaker and Rack Starter Kit

AC/DC input 115 V AC (USA Compatible Plug)

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Ascentisยฎ Express Biphenyl Column

2.7 μm particle size, L ร— I.D. 10 cm ร— 2.1 mm

CONDITIONS

extraction tube

SupelQue Non-buffered tube 2 (55295-U)

extraction process

Transfer the solution into 50 mL plastic tube (55248-U); add 10 mL acetonitrile; shake for 1 minute by hand; add contents of the Supel QuE Non-Buffered Extraction Tube 2 (55295-U); (shake for 5 minutes using QuEChERS shaker (55278-U); centrifuge for 5 minutes at 5000 rpm; collect top acetonitrile layer; no cleanup is required.)

column

Ascentis Express Biphenyl, 10cm x 2.1mm, 2.7 μm particles (64065-U)

mobile phase

(A) 0.1% TFA in water; (B) 0.1% TFA in acetonitrile

gradient

47% B to 50% B in 13 min.; 100% B in 0.1 min; held at 100% B for 3 min; 47% B in 0.1 min; held at 47% B for 2.5 min.

flow rate

0.7 mL/min

pressure

5000 psi (345 bar)

column temp.

35 ยฐC

detector

UV, 220 nm

injection

5 μL

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dissolve in heated water, 1 gummy candy in 20 mL

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Ascentis is a registered trademark of Merck KGaA, Darmstadt, Germany