- A non-classical copper carbonyl on a tri-alkene hydrocarbon support.
A non-classical copper carbonyl on a tri-alkene hydrocarbon support.
Dalton transactions (Cambridge, England : 2003) (2009-03-11)
Mauro Fianchini, Thomas R Cundari, Nathan J DeYonker, H V Rasika Dias
PMID19274285
초록
Two rare copper complexes, a tri-alkene adduct [Cu(ttt-cdt)(FSbF(5))] and a non-classical carbon monoxide complex [Cu(ttt-cdt)(CO)][SbF(6)] with a high CO stretching frequency ([small nu, Greek, macron](CO) = 2160 cm(-1)), have been isolated using trans,trans,trans-1,5,9-cyclododecatriene (ttt-cdt) ligand.
MATERIALS