- Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature.
Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature.
Molecules (Basel, Switzerland) (2012-11-22)
Chun-Wei Kuo, Min-Tsang Hsieh, Shijay Gao, Yi-Ming Shao, Ching-Fa Yao, Kak-Shan Shia
PMID23169264
초록
Upon treatment with phenyl dichlorophosphate (PhOP=OCl(2)) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.
MATERIALS