- Nucleophilic substitution reaction at the nitrogen of arylsulfonamides with phosphide anion.
Nucleophilic substitution reaction at the nitrogen of arylsulfonamides with phosphide anion.
Journal of the American Chemical Society (2012-11-16)
Suguru Yoshida, Kazunobu Igawa, Katsuhiko Tomooka
PMID23151262
초록
A novel nucleophilic substitution reaction at the nitrogen of arylsulfonamides by means of phosphide anions has been described. This reaction allows for the efficient transformation of arylsulfonamides into synthetically valuable phosphamides, amines, and a variety of protected amines.
MATERIALS