Highly enantioselective transfer hydrogenation of fluoroalkyl ketones.

Highly enantioselective transfer hydrogenation of fluoroalkyl ketones.

Organic letters (2006-12-15)

Damjan Sterk, Michel Stephan, Barbara Mohar

초록

[Structure: see text] The asymmetric transfer hydrogenation of fluoroalkyl ketones mediated by [Ru(eta6-arene)((S,S)-R2NSO2DPEN)] catalysts using HCO2H-Et3N afforded the corresponding alcohols with high ee's and in excellent yields.

MATERIALS

제품 번호

브랜드

제품 설명

701769

Sigma-Aldrich

Dichloro(mesitylene)ruthenium(II) dimer, 95%