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Merck
모든 사진(3)

Key Documents

C409

Sigma-Aldrich

(1R,3S)-(+)-Camphoric acid

99%

동의어(들):

(+)-Camphoric acid, (1R,3S)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid

로그인조직 및 계약 가격 보기


About This Item

실험식(Hill 표기법):
C10H16O4
CAS Number:
Molecular Weight:
200.23
Beilstein:
2050204
EC Number:
MDL number:
UNSPSC 코드:
51113400
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

99%

형태

powder

광학 활성

[α]20/D 46°, c = 1 in ethanol

mp

183-186 °C (lit.)

SMILES string

CC1(C)[C@H](CC[C@@]1(C)C(O)=O)C(O)=O

InChI

1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m1/s1

InChI key

LSPHULWDVZXLIL-LDWIPMOCSA-N

일반 설명

Camphoric acid is a diacid, generally prepared by the oxidation of terpene (+)-camphor. It can be used as a chirality inducing agent in some organic reactions.

애플리케이션

(1R,3S)-(+)-Camphoric acid may be used in the preparation (1R,2S,3R,5S)-2,3-dibenzyl-1,8,8-trimethyl-3-thianiumbicyclo[3.2.1]octane perchlorate. It reacts with uranyl nitrate in pyridine(py) or py/methanol(MeOH) to form novel uranyl-organic assemblages.

픽토그램

Exclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


시험 성적서(COA)

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Preparation of optically active epoxides via sulfur ylides. Origin of the chiral induction.
Breau L and Durst T.
Tetrahedron Asymmetry, 2(5), 367-370 (1991)
Synthesis, characterization, and water-degradation of biorenewable polyesters derived from natural camphoric acid
Nsengiyumva O and Miller SA
Green Chemistry, 21(5), 973-978 (2019)
Solvothermal Synthesis and Crystal Structure of Uranyl Complexes with 1, 1-Cyclobutanedicarboxylic and (1R, 3S)-(+)-Camphoric Acids-Novel Chiral Uranyl-Organic Frameworks.
Thuery P.
European Journal of Inorganic Chemistry, 2006(18), 3646-3651 (2006)
Spontaneous resolution to absolute chiral induction: pseudo-kagome type homochiral Zn (II)/Co (II) coordination polymers with achiral precursors
Bisht KK and Suresh E
Journal of the American Chemical Society, 135(42), 15690-15693 (2013)
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Nature communications, 2, 586-586 (2011-12-14)
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