추천 제품
분석
97%
형태
liquid
refractive index
n20/D 1.4 (lit.)
bp
167.7 °C/773 mmHg (lit.)
mp
−19-−18 °C (lit.)
density
0.929 g/mL at 25 °C (lit.)
SMILES string
CCOC(OCC)C#N
InChI
1S/C6H11NO2/c1-3-8-6(5-7)9-4-2/h6H,3-4H2,1-2H3
InChI key
UDELMRIGXNCYLU-UHFFFAOYSA-N
일반 설명
Diethoxyacetonitrile is a 2,2-dialkoxyalkanenitrile derivative. Reaction of hydrocyanic acid with various ortho esters of aliphatic and aromatic acids in the presence of acidic catalyst has been reported to afford diethoxyacetonitrile. Houben-Hoesch reaction of diethoxyacetonitrile with 1,2,4-trimethoxybenzene affords tris(2,4,5-trimethoxyphenyl)methane.
애플리케이션
Diethoxyacetonitrile may be used in the preparation of methyl 5-diethoxymethylimidazole-4-carboxylate, via anionic cycloaddition reaction with methyl isocyanoacetate.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
120.2 °F - closed cup
Flash Point (°C)
49 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
An anomalous Houben-Hoesch reaction and some applications in arylation reactions.
Sanchez-Viesca F, et al.
Organic Prep. and Proc. Int., 36(2), 135-140 (2004)
2, 2-Dialkoxyalkanenitriles.
Erickson JG.
Journal of the American Chemical Society, 73(3), 1338-1339 (1951)
An efficient synthesis of 5-diethoxymethylimidazole-4-carboxylate, a potential precursor for various imidazole derivatives.
Murakami T, et al.
Tetrahedron Letters, 23(45), 4729-4732 (1982)
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