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Merck
모든 사진(3)

주요 문서

289426

Sigma-Aldrich

4,4′−Dipyridyl

98%

동의어(들):

4,4′-Bipyridyl, 4,4′-Bipyridine

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About This Item

실험식(Hill 표기법):
C10H8N2
CAS Number:
Molecular Weight:
156.18
Beilstein:
113176
EC Number:
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.23

Quality Level

분석

98%

형태

powder

bp

305 °C (lit.)

mp

109-112 °C (lit.)

SMILES string

c1cc(ccn1)-c2ccncc2

InChI

1S/C10H8N2/c1-5-11-6-2-9(1)10-3-7-12-8-4-10/h1-8H

InChI key

MWVTWFVJZLCBMC-UHFFFAOYSA-N

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일반 설명

4,4′-Dipyridyl (BPY) is an organic linker mainly used in the preparation of coordination polymers. It is a pyridine derivative in which pyridyl groups can rotate along the carbon-carbon structure. It can be used as a catalyst for photoelectrochemical reduction.
4,4′-bpy is popularly used to bridge metal centers to form coordination polymers with novel properties. 4,4′-bpy ligands can mediate electronic effects between paramagnetic metals ions by stabilizing the magnetic ordering.

애플리케이션

4,4′-Dipyridyl (4,4′-bipyridine, 4,4′-bpy) and Co (NCS)2 solutions were interdifussed to form single crystals Co(NCS)2(4,4′-bipy)2·2(CH3CH2)2O and Co(NCS)2(4,4′-bipy)2·2(CH3CH2)2O.
BPY is a ligand that forms a network between the transition metals which results in the formation of coordination bond. Hybrid nanosheets can be prepared by using a coordination polymer and BPY as a complex linker. It consists of two active sites which can be used for the development of drugs.

픽토그램

Skull and crossbones

신호어

Danger

유해 및 위험 성명서

예방조치 성명서

Hazard Classifications

Acute Tox. 3 Oral

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Coordination Polymers of Co(NCS)2 with Pyrazine and 4,4`-Bipyridine:? Syntheses and Structures
Lu J, et al.
Inorganic Chemistry, 36 (5), 923-929 null
Bottom-up approach for the preparation of hybrid nanosheets based on coordination polymers made of metal-diethyloxaloacetate complexes linked by 4, 4′-bipyridine.
Portoles-Gil N, et al.
CrystEngComm, 19(34), 4972-4982 (2017)
Crystal engineering of coordination polymers using 4, 4′-bipyridine as a bond between transition metal atoms.
Biradha K, et al.
Chemical Communications (Cambridge, England), 138(40), 4169-4179 (2006)
Ultrafast photoinduced interfacial proton coupled electron transfer from cdse quantum dots to 4, 4′-bipyridine.
Chen J, et al.
Journal of the American Chemical Society, 138(3), 884-892 (2016)
Kumar Biradha et al.
Chemical communications (Cambridge, England), (40)(40), 4169-4179 (2006-10-13)
Coordination polymers have attracted an enormous interest among chemists due to their novel physical and chemical properties. This review describes the role of 4,4'-bipyridine in discovering various coordination polymers with novel topologies that range from one-dimensional to three dimensional. The

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