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Core/Shell Face-Centered Tetragonal FePd/Pd Nanoparticles as an Efficient Non-Pt Catalyst for the Oxygen Reduction Reaction.

Core/Shell Face-Centered Tetragonal FePd/Pd Nanoparticles as an Efficient Non-Pt Catalyst for the Oxygen Reduction Reaction.

ACS nano (2015-10-06)

Guangming Jiang, Huiyuan Zhu, Xu Zhang, Bo Shen, Liheng Wu, Sen Zhang, Gang Lu, Zhongbiao Wu, Shouheng Sun

ABSTRACT

We report the synthesis of core/shell face-centered tetragonal (fct)-FePd/Pd nanoparticles (NPs) via reductive annealing of core/shell Pd/Fe3O4 NPs followed by temperature-controlled Fe etching in acetic acid. Among three different kinds of core/shell FePd/Pd NPs studied (FePd core at ∼8 nm and Pd shell at 0.27, 0.65, or 0.81 nm), the fct-FePd/Pd-0.65 NPs are the most efficient catalyst for the oxygen reduction reaction (ORR) in 0.1 M HClO4 with Pt-like activity and durability. This enhanced ORR catalysis arises from the desired Pd lattice compression in the 0.65 nm Pd shell induced by the fct-FePd core. Our study offers a general approach to enhance Pd catalysis in acid for ORR.

MATERIALS

Product Number

Brand

Product Description

Sigma-Aldrich

Acetic acid-¹²C₂, 99.9 atom % ¹²C

Supelco

Ethanol solution, certified reference material, 2000 μg/mL in methanol

Sigma-Aldrich

Isopropyl alcohol, ≥99.7%, FCC, FG

Sigma-Aldrich

Acetic acid, ≥99.5%, FCC, FG

Sigma-Aldrich

Acetic acid, natural, ≥99.5%, FG

Sigma-Aldrich

Acetic acid, for luminescence, BioUltra, ≥99.5% (GC)

Sigma-Aldrich

Acetic acid, glacial, ACS reagent, ≥99.7%

Sigma-Aldrich

Ethanol, absolute, denaturated with 0.5-1.5 Vol.% 2-butanone and approx. 0.001% Bitrex (GC), ≥98% (GC)

Sigma-Aldrich

Acetic acid solution, suitable for HPLC

Sigma-Aldrich

Acetic acid, glacial, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.8%

Sigma-Aldrich

Acetic acid, glacial, puriss., 99-100%

Sigma-Aldrich

Acetic acid, glacial, ≥99.99% trace metals basis

Sigma-Aldrich

Acetic acid, glacial, ReagentPlus^®, ≥99%

Sigma-Aldrich

Acetic acid, glacial, puriss., meets analytical specification of Ph. Eur., BP, USP, FCC, 99.8-100.5%

Sigma-Aldrich

5α-Androstan-17β-ol-3-one, ≥97.5%

Sigma-Aldrich

2-Propanol, for molecular biology, BioReagent, ≥99.5%

Sigma-Aldrich

2-Propanol, BioUltra, for molecular biology, ≥99.5% (GC)

Sigma-Aldrich

5α-Androstan-17β-ol-3-one, purum, ≥99.0% (TLC)

Sigma-Aldrich

Isopropyl alcohol, meets USP testing specifications

Sigma-Aldrich

Ethanol, ACS reagent, prima fine spirit, without additive, F15 o¹

Sigma-Aldrich

Hexane, ReagentPlus^®, ≥99%

Sigma-Aldrich

2-Propanol, Laboratory Reagent, ≥99.5%

Sigma-Aldrich

1,2,3,4-Tetrahydronaphthalene, ReagentPlus^®, 99%

Sigma-Aldrich

2-Propanol, puriss. p.a., ACS reagent, ≥99.8% (GC)

Sigma-Aldrich

Hexane, Laboratory Reagent, ≥95%

Sigma-Aldrich

2-Propanol, ACS reagent, ≥99.5%

Sigma-Aldrich

2-Propanol, puriss., meets analytical specification of Ph. Eur., BP, USP, ≥99.5% (GC)

Sigma-Aldrich

Ethyl alcohol, Pure, 200 proof, ACS reagent, ≥99.5%