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Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Molecules (Basel, Switzerland) (2013-05-28)

Jana Doháňošová, Tibor Gracza

ABSTRACT

The palladium (II)-catalysed reactions of alkenols and aminoalkenols such as oxycarbonylations or bicyclisations are powerful methods for the construction of oxygen and nitrogen-containing heterocyclic compounds. This review highlights recent progress in the development of the asymmetric palladium(II)-catalysed Wacker-type cyclisations of unsaturated polyols and aminoalcohols. The scope, limitations, and applications of these reactions are presented.

MATERIALS

Product Number

Brand

Product Description

Palladium, foil, not light tested, 100x100mm, thickness 0.025mm, as rolled, 99.99+%

Palladium, foil, not light tested, 25x25mm, thickness 0.003mm, 99.95%

Palladium, foil, light tested, 100x100mm, thickness 0.025mm, as rolled, 99.95%

Palladium, foil, light tested, 100x100mm, thickness 0.025mm, as rolled, 99.99+%

Palladium, foil, 6mm disks, thickness 0.125mm, as rolled, 99.95%

Palladium, foil, 8mm disks, thickness 0.008mm, 99.95%

Palladium, foil, 8mm disks, thickness 0.03mm, as rolled, 99.95%

Palladium, foil, 8mm disks, thickness 0.025mm, as rolled, 99.95%

Palladium, foil, 6mm disks, thickness 0.075mm, as rolled, 99.95%

Palladium, foil, 25x25mm, thickness 0.1mm, as rolled, 99.99+%

Palladium, foil, 10mm disks, thickness 0.047mm, as rolled, 99.95%

Palladium, foil, 25x25mm, thickness 0.25mm, as rolled, 99.95%

Palladium, foil, 15mm disks, thickness 0.025mm, as rolled, 99.99+%

Palladium, foil, 0.2m coil, thickness 0.1mm, coil width 2mm, as rolled, 99.95%

Palladium, foil, 25mm disks, thickness 0.02mm, as rolled, 99.95%

Palladium, foil, 10mm disks, thickness 0.075mm, as rolled, 99.95%

Palladium, foil, 25x25mm, thickness 0.25mm, as rolled, 99.99+%

Palladium, foil, 4mm disks, thickness 0.047mm, as rolled, 99.95%

Palladium, foil, 6mm disks, thickness 0.025mm, as rolled, 99.99+%

Palladium, foil, 10mm disks, thickness 0.125mm, as rolled, 99.95%

Palladium, foil, 4mm disks, thickness 0.075mm, as rolled, 99.95%

Palladium, foil, 15mm disks, thickness 0.03mm, as rolled, 99.95%

Palladium, foil, 10mm disks, thickness 0.006mm, 99.95%

Palladium, foil, 6mm disks, thickness 0.02mm, as rolled, 99.95%

Palladium, foil, 10mm disks, thickness 0.25mm, as rolled, 99.95%

Palladium, foil, 25x25mm, thickness 0.50mm, as rolled, 99.99+%

Palladium, foil, 4mm disks, thickness 0.125mm, as rolled, 99.95%

Palladium, foil, 15mm disks, thickness 0.047mm, as rolled, 99.95%

Palladium, foil, 6mm disks, thickness 0.03mm, as rolled, 99.95%

Palladium, foil, 4mm disks, thickness 0.006mm, 99.95%