- Using Voltammetry to Measure the Relative Hydrogen-Bonding Strengths of Pyridine and Its Derivatives in Acetonitrile.
Using Voltammetry to Measure the Relative Hydrogen-Bonding Strengths of Pyridine and Its Derivatives in Acetonitrile.
Chemphyschem : a European journal of chemical physics and physical chemistry (2017-06-14)
Malcolm E Tessensohn, Yu Rong Koh, Sihao Lim, Hajime Hirao, Richard D Webster
PMID28608640
要旨
The voltammetric behavior of 2,3,5,6-tetramethyl-1,4-phenylenediamine was found to be able to differentiate the hydrogen acceptor abilities of electroinactive pyridine compounds in acetonitrile. Weak and strong hydrogen acceptors were distinguished through the onset of a third oxidation process that came about at sub-stoichiometric amounts of strong hydrogen acceptors, but not in the presence of weak hydrogen acceptors. This additional oxidation reaction occurred at a potential between the two 1 e