1.01245

Isopentyl nitrite

extra pure stabilized with potassium carbonate

• 別名: Isopentyl nitrite, iso-Amyl nitrite, iso-Pentyl nitrite, Nitrous acid isoamyl ester
• 実験式（ヒル表記法）: C₅H₁₁NO₂
• CAS番号: 110-46-3
• 分子量: 117.15
• MDL番号: MFCD00002057
• UNSPSCコード: 12352108
• EC Index Number: 203-770-8
• NACRES: NA.22

特性

• 品質水準: 200
• 形状: liquid
• 自己発火温度: 208 °C
• 有効性: 505 mg/kg LD₅₀, oral (Rat)
• bp: 97-99 °C/1013 hPa
• 転移温度: flash point -18 °C
• 密度: 0.872 g/cm³ at 20 °C
• 保管温度: 2-8°C
• InChI: 1S/C5H11NO2/c1-5(2)3-4-8-6-7/h5H,3-4H2,1-2H3
• InChI Key: OWFXIOWLTKNBAP-UHFFFAOYSA-N

詳細

アプリケーション

• Deaminative coupling of benzylamines and arylboronic acids: Research demonstrated the use of isopentyl nitrite in the deaminative coupling of benzylamines and arylboronic acids, showcasing its application in creating complex molecules for pharmaceutical and chemical manufacturing processes (Sirvinskaite, Reisenbauer, and Morandi, 2023).
• Syntheses of Arylazo Phosphine Oxides and Phosphonates: Utilizing isopentyl nitrite, research facilitated the synthesis of arylazo phosphine oxides and phosphonates via N-P bond formation under blue LED light conditions, contributing to developments in organophosphorus chemistry (Shen et al., 2022).

アナリシスノート

Total nitrites (GC): ≥ 97.0 % (a/a)
Identity (IR-spectrum): conforms
Free acid: conforms
Density (d 20 °C/ 4 °C): 0.8720 - 0.8770
Non volatile matter: ≤ 0.04 %

安全性情報

• ピクトグラム: GHS02,GHS05,GHS07,GHS08
• シグナルワード: Danger
• 危険有害性情報: H225 - H302 + H332 - H314 - H317 - H341
• 注意書き: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): -4.0 °F - closed cup
• 引火点(℃): -20 °C - closed cup