421804

(1S,2S)-trans-1,2-シクロヘキサンジオール

99%

• 別名: (1S)-trans-1,2-シクロヘキサンジオール
• 化学式: C₆H₁₀(OH)₂
• CAS番号: 57794-08-8
• 分子量: 116.16
• Beilstein: 1901343
• MDL番号: MFCD00066431
• UNSPSCコード: 12352001
• PubChem Substance ID: 24866402
• NACRES: NA.22

特性

• アッセイ: 99%
• 光学活性: [α]20/D +39°, c = 1.6 in H₂O
• 光学純度: ee: 99% (GLC)
• mp: 107-109 °C (lit.)
• SMILES記法: O[C@H]1CCCC[C@@H]1O
• InChI: 1S/C6H12O2/c7-5-3-1-2-4-6(5)8/h5-8H,1-4H2/t5-,6-/m0/s1
• InChI Key: PFURGBBHAOXLIO-WDSKDSINSA-N

詳細

アプリケーション

(1S,2S)-trans-1,2-Cyclohexanediol may be used in the preparation of (1S,2S)-1,2-cyclohexanediyl bis(4-vinylbenzoate) by reacting with 4-vinylbenzoyl chloride. It may also be used as a chiral ligand for the preparation of non-racemic hydroxy phosphonates via titanium alkoxide-catalyzed addition of dimethyl phosphite to the corresponding aldehydes.

C₂-symmetric chiral diol with versatile applications as a chiral auxiliary, building block, and chiral ligand.

安全性情報

• ピクトグラム: GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H318,H335
• 注意書き: P261 - P280 - P305 + P351 + P338
• 危険有害性の分類: Eye Dam. 1 - STOT SE 3
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): dust mask type N95 (US), Eyeshields, Gloves