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31461

Supelco

Carbophenothion

PESTANAL®, analytical standard

Synonym(s):

S-(4-Chlorophenylthiomethyl) O,O-diethyl phosphorodithioate

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About This Item

Empirical Formula (Hill Notation):
C11H16ClO2PS3
CAS Number:
786-19-6
Molecular Weight:
342.87
Beilstein:
1885240
EC Number:
212-324-1
MDL number:
MFCD00128009
UNSPSC Code:
41116107
PubChem Substance ID:
329753775
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CCOP(=S)(OCC)SCSc1ccc(Cl)cc1

InChI

1S/C11H16ClO2PS3/c1-3-13-15(16,14-4-2)18-9-17-11-7-5-10(12)6-8-11/h5-8H,3-4,9H2,1-2H3

InChI key

VEDTXTNSFWUXGQ-UHFFFAOYSA-N

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General description

Carbophenothion is an organophosphorus pesticide which is highly toxic through ingestion as well as skin absorption. It is mostly used as non-systemic insecticide and acaricide.

Application

Carbophenothion may have been used as internal standard for identification and characterisation of organochlorine and organophosphorus pesticides in Brazil′s medicinal plants like Passiflora L. using high-resolution gas chromatography with electron-capture and flame photometric detection (HRGC–ECD/FPD).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

Signal Word

Danger

Hazard Statements

H300,H311,H410

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

31461-BULK:
31461-VAR:
31461-250MG:4548173293141

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ1103
BCBW3097
SZBC272XV
SZBA246XV
SZBA246X

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Evaluation of organophosphorus pesticide residues in citrus fruits from the Valencian community (Spain).
Torres CM
Journal of AOAC (Association of Official Analytical Chemists) International, 80(5), 1122-1128 (1997)
Fast supercritical fluid extraction and high-resolution gas chromatography with electron-capture and flame photometric detection for multiresidue screening of organochlorine and organophosphorus pesticides in Brazil's medicinal plants.
Zuin VG, Yariwake JH, Bicchi C.
Journal of Chromatography A, 985(1-2), 159-166 (2003)
T.S.S. Dikshith
Handbook of Chemicals and Safety, 167-167 (2016)
S Sánchez-Fortún et al.
Environmental toxicology and chemistry, 20(9), 2008-2013 (2001-08-28)
The acute toxicity of carbophenothion to three age classes of Artemia salina was evaluated. An increase in toxicity of carbophenothion was found following longer development of A. salina. The effect of pretreatment with the nonselective muscarinic antagonist atropine, the two
Dislodgeable residues of carbophenothion in Florida citrus: implications for safe worker reentry.
G C de Batista et al.
Bulletin of environmental contamination and toxicology, 35(2), 213-221 (1985-08-01)
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Protocols

US EPA Method 8141: GC Analysis of Organophosphorus Pesticides (OP-Pest) on Equity®-5, NPD Detection

analytical standard; Tokuthion, technical grade, pkg of 50 mg; Crotoxyphos; Phorate; Azinphos-ethyl; Diazinon; Azinphos-methyl; Demeton-O; Dimethoate; Chlorpyrifos-methyl

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