Cis double allylation of cyclopropenes using cyclopropylindium reagents.

Cis double allylation of cyclopropenes using cyclopropylindium reagents.

Organic & biomolecular chemistry (2007-06-22)

Tsunehisa Hirashita, Fumio Shiraki, Kenji Onishi, Mamiko Ogura, Shuki Araki

ABSTRACT

The successive double allylation of cyclopropenes with allylindium sesquiiodide and allyl iodide proceeded with a cis-addition mode in the presence of other organometallics (e.g. Grignard reagent, cuprate, Et(2)Zn and Et(3)Al), giving the corresponding cis-diallylcyclopropanes in high yields.

MATERIALI

N° Catalogo

Marchio

Descrizione del prodotto

238325

Sigma-Aldrich

Allyl iodide, 98%