Chemoenzymatic synthesis of the alarm pheromone (+)-verbenone from geranyl diphosphate.

Chemoenzymatic synthesis of the alarm pheromone (+)-verbenone from geranyl diphosphate.

Chemical communications (Cambridge, England) (2012-06-12)

Zulfa Yoosuf-Aly, Juan A Faraldos, David J Miller, Rudolf K Allemann

ABSTRACT

The enzyme-guided asymmetric synthesis of (+)-verbenone from geranyl diphosphate in a simple two-step, one pot transformation highlights the potential of chemoenzymatic procedures for the generation of high-value terpenoids.

MATERIALI

N° Catalogo

Marchio

Descrizione del prodotto

W506907

Sigma-Aldrich

(1S)-(−)-Verbenone, ≥93%

218251

Sigma-Aldrich

(1S)-(−)-Verbenone, 94%

94882

Supelco

(1S)-(−)-Verbenone, analytical standard