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447218

Sigma-Aldrich

Trimethyl borate

99.999% (trace metal basis)

Sinonimo/i:

Boric acid trimethyl ester, Methyl borate

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About This Item

Formula condensata:
B(OCH3)3
Numero CAS:
Peso molecolare:
103.91
Beilstein:
1697939
Numero CE:
Numero MDL:
Codice UNSPSC:
12352103
ID PubChem:
NACRES:
NA.22

Densità del vapore

3.59 (vs air)

Livello qualitativo

Saggio

99.999% (trace metal basis)

Indice di rifrazione

n20/D 1.346 (lit.)

P. eboll.

68-69 °C (lit.)

Punto di fusione

−34 °C (lit.)

Densità

0.932 g/mL at 20 °C (lit.)

Stringa SMILE

COB(OC)OC

InChI

1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3
WRECIMRULFAWHA-UHFFFAOYSA-N

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Confezionamento

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Note legali

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Avvertenze

Danger

Classi di pericolo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 1B - STOT SE 1

Organi bersaglio

Eyes

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

12.2 °F - (own results)

Punto d’infiammabilità (°C)

-11 °C - (own results)

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Certificati d'analisi (COA)

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Analytical chemistry, 80(9), 3416-3421 (2008-03-28)
A mass spectrometric method has been developed for the identification of the carboxylic acid functional group in analytes evaporated and ionized by electrospray ionization (ESI). This method is based on gas-phase ion-molecule reactions of ammoniated ([M + NH4]+) and sodiated
Scott Gronert et al.
Journal of the American Society for Mass Spectrometry, 13(9), 1088-1098 (2002-09-27)
Using a quadrupole ion trap mass spectrometer, trimethyl borate was allowed to react with dihydrogen phosphate, deprotonated O-phosphoserine, and a set of hydrogen bonded complexes involving dihydrogen phosphate and neutral acids (phosphoric acid, acetic acid, serine, and O-phosphoserine). The reactions
Jayalakshmi Somuramasami et al.
Journal of the American Society for Mass Spectrometry, 22(6), 1040-1051 (2011-09-29)
Several lignin model compounds were examined to test whether gas-phase ion-molecule reactions of trimethylborate (TMB) in a FTICR can be used to differentiate the ortho-, meta-, and para-isomers of protonated aromatic compounds, such as those formed during degradation of lignin.
Ryan J Eismin et al.
Journal of the American Society for Mass Spectrometry, 23(1), 12-22 (2011-10-18)
A mass spectrometric method has been delineated for the identification of the epoxide functionalities in unknown monofunctional analytes. This method utilizes gas-phase ion/molecule reactions of protonated analytes with neutral trimethyl borate (TMB) followed by collision-activated dissociation (CAD) in an ion

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