399299

trans-4-Methoxy-β-nitrostyrene

99%

• Linear Formula: CH₃OC₆H₄CH=CHNO₂
• CAS Number: 5576-97-6
• Molecular Weight: 179.17
• MDL number: MFCD00024826
• UNSPSC Code: 12352100
• PubChem Substance ID: 24864801
• NACRES: NA.22

Properties

• Assay: 99%
• mp: 86-88 °C (lit.)
• solubility: chloroform: soluble 25 mg/mL, clear, yellow
• SMILES string: [H]\C(=C(\[H])[N+]([O-])=O)c1ccc(OC)cc1
• InChI: 1S/C9H9NO3/c1-13-9-4-2-8(3-5-9)6-7-10(11)12/h2-7H,1H3/b7-6+
• InChI key: JKQUXSHVQGBODD-VOTSOKGWSA-N

Description

General description

trans-4-Methoxy-β-nitrostyrene participates in the Michael reaction on carbapenam intermediate.

Application

trans-4-Methoxy-β-nitrostyrene acts as guest molecule and forms guest molecules forming co-crystal phases with the d-form of robust syndiotactic polystyrene (sPS). It may be employed as a Michael acceptor in the synthesis of proline based chiral ionic liquid catalysts with two five-membered unsaturated aza-heterocycles.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves