900542
(2S)-2-Phenyl-3,4-dihydro-2H-pyrimido[2,1-b][1,3]benzothiazole
95%
Synonym(s):
Birman (S)-HBTM Resolution Catalyst
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About This Item
Empirical Formula (Hill Notation):
C16H14N2S
CAS Number:
Molecular Weight:
266.36
UNSPSC Code:
12161600
NACRES:
NA.22
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Quality Level
Assay
95%
form
powder or chunks
mp
125 °C
storage temp.
2-8°C
SMILES string
C12=CC=CC=C1SC3=N[C@H](C4=CC=CC=C4)CCN23
Application
Organocatalyst for the kinetic resolution of secondary alcohols by acylation with anhydrides.
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Description
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Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Ximin Li et al.
The Journal of organic chemistry, 77(4), 1722-1737 (2012-01-31)
Kinetic resolution of racemic alcohols has been traditionally achieved via enzymatic enantioselective esterification and ester hydrolysis. However, there has long been considerable interest in devising nonenzymatic alternative methods for this transformation. Amidine-based catalysts (ABCs), a new class of enantioselective acyl
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