Selective Recognition of Herbicides in Water Using a Fluorescent Molecularly Imprinted Polymer Sensor.

Fluorescent molecularly imprinted polymer (FMIP) optosensor was utilized for the selective identification of 2,4-dichlorophenoxacetic acid (2,4-D) due to worldwide pollution caused by using herbicides in agricultural industry. In this regards, two derivatives of polymerizable 1,8-naphthalimide namely, 1,8-naphthalimide containing thiourea (NI) and diethyl amine tagged 1,8-naphthalimide (NII) were used as the receptors and 2,4-D was applied as a template. Also, precipitation polymerization was applied to prepare the fluorescent molecularly imprinted polymer (FMIP). The morphological, structural and thermal analysis was carried out using SEM, TEM, EDS, BET, FTIR, DSC and TGA for characterizing the fluorescent optosensor. The adsorption efficiency of FMIP and FNIP was studied using Langmuir, Freundlich, BET and Redlich Peterson isotherms. The results represented that the adsorption of 2,4-D on FMIP and FNIP agreed the Freundlich adsorption isotherm with correlation coefficient of 0.9935 and 0.9801, respectively. The prepared sensor was able for the selective determination of 2,4-D salt in the linear range of 5 × 10-7-1 × 10-3 M with a limit of detection of 16.8 nM. The present study revealed that the FMIP prepared by 1,8-naphthalimide derivative (NI) could potentially recognize the trace concentration of 2,4-D. Graphical Abstract Graphical abstract of flourescene switching mechanism in a fluorescent molecularly imprinted polymer sensor.