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KITALYSIS-PHO

Sigma-Aldrich

KitAlysis High-Throughput 24-Catalyst Photoredox Reaction Screening Kit-Pack of 2

Synonym(s):

high-throughput photoredox catalyst screening kit

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About This Item

UNSPSC Code:
12161600
NACRES:
NA.22

reaction suitability

reagent type: catalyst
reaction type: Photocatalysis

Application

Screening kit for photocatalytic reactions to be used with Photo KitAlysis Starter Kit. Step-by-step user guide is provided in the below hyperlink.
Step-by-Step Guide for Photocatalysis Reaction Screening Kit
Downloadable experimental excel file

Each kit contains 2 customizable screening sets that include the following components:
  • 24 pre-weighed catalysts in glass vials loaded with stir bars and topped with cap mat
  • 4 degassed anhydrous solvents (DCM, DCE, DMF, MeCN)
  • 1 NEW KitAlysis 24-Well Reaction Block Replacement Film
  • 4 empty substrate stock solution reaction vials with stirbars
  • 1 internal standard

For use Photo KitAlysis High-Throughput Screen Platform (sold seperately)Monitor reaction progress via TLC-MS by following this protocol

Best when used with KitAlysis Benchtop Inertion Box (sold separately).

Features:
  • Designed and tested by synthetic chemists
  • Easily run 24-microscale reactions in parallel
  • 10 μmol reactions with 1 μmol catalyst, 0.1 M concentration
  • Customizable Excel Template for quick calculations and easy incorporation into electronic laboratory notebooks

Legal Information

KitAlysis is a trademark of Sigma-Aldrich Co. LLC

Kit Components Also Available Separately

Product No.
Description
SDS

  • 224758Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate, powderSDS

  • 232017Tetrachloro-1,4-benzoquinone, 99%SDS

  • 2723452,4,6-Triphenylpyrylium tetrafluoroborate, 98%SDS

  • 318337Acridine Orange hydrochloride hydrate, ≥98% (HPLC)SDS

  • 333190Bismuth(III) sulfide, 99%SDS

  • 343714Dichlorotris(1,10-phenanthroline)ruthenium(II) hydrate, 98%SDS

  • 4598529,10-Anthracenedicarbonitrile, 97%SDS

  • 46955Fluorescein, for fluorescence, free acidSDS

  • 637017Bismuth(III) oxide, nanopowder, 90-210 nm particle size, 99.8% trace metals basisSDS

  • 688096Tris[2-phenylpyridinato-C2,N]iridium(III), 97%SDS

  • 747769[Ir(dtbbpy)(ppy)2]PF6SDS

  • 747777[Ru(bpz)3][PF6]2, 95%SDS

  • 747785[Ru(bpm)3][Cl]2SDS

  • 747793(Ir[dF(CF3)ppy]2(dtbpy))PF6SDS

  • 7932219-Mesityl-10-phenylacridinium tetrafluoroborateSDS

  • 7938769-Mesityl-2,7-dimethyl-10-phenylacridinium tetrafluoroborateSDS

  • 7941719-Mesityl-10-methylacridinium tetrafluoroborateSDS

  • 804215[Ir{dFCF3ppy}2(bpy)]PF6SDS

  • 9004219-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate, ≥95%SDS

  • 9006922,4,6-Tris(4-methoxyphenyl)pyrylium tetrafluoroborateSDS

  • 9006939-Mesityl-1,3,6,8-tetramethoxy-10-phenylacridin-10-ium tetrafluoroborate, 95%SDS

  • 90069410-(3,5-Dimethoxyphenyl)-9-mesityl-1,3,6,8-tetramethoxyacridin-10-ium tetrafluoroborate, ≥93%SDS

  • D604002,3-Dichloro-5,6-dicyano-p-benzoquinone, 98%SDS

  • P2508Proflavine hemisulfate salt hydrate, powderSDS

  • 900633Dichloromethane, anhydrous, contains 40-150 ppm amylene as stabilizer, ZerO2®, ≥99.8%SDS

  • 9006371,2-Dichloroethane, anhydrous, ZerO2®, 99.8%SDS

  • 900638N,N-Dimethylformamide, anhydrous, ZerO2®, 99.8%SDS

  • 900644Acetonitrile, anhydrous, ZerO2®, 99.8%SDS

  • B34656Biphenyl, ReagentPlus®, 99.5%SDS

  • Z118850Spinbar® magnetic stirring fleas, red, L 10 mm, diam. 3 mmSDS

See All (30)

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 2 - Repr. 1B - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3

Target Organs

Central nervous system, Kidney, Respiratory system

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

35.6 °F - closed cup

Flash Point(C)

2.0 °C - closed cup


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Articles

The Photo KitAlysis Photoreactor Controller allows you maximum control of photocatalysis reactions.

The PhotoKitAlysis Reaction Kit was designed to provide the best possible chance of finding good reaction conditions for cross-coupling reactions: pre-weighed base or base solution (provided), 10–20 mmol coupling partner (user supplied), 10 mmol aryl halide substrate (user supplied), Catalysts (user supplied), 6 solvents (toluene, DMA. THJF, n-butanol, MeOH, MeCN) (provided).

Protocols

Materials and procedure Step-by-Step Guide for Photocatalysis High-Throughput Reaction Screening Kit

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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