sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

GF68100454

Nickel, wire reel, 10m, diameter 0.125mm, annealed, 99.98%

GF08224321

Nickel, foil, 5m coil, thickness 0.025mm, annealed, 99%

GF72595659

Nickel, foil, 5m coil, thickness 0.05mm, annealed, 99%

GF92598283

Nickel, foil, 5m coil, thickness 0.0125mm, 99.9%

GF82156912

Nickel, rod, 100mm, diameter 12.0mm, 99%

GF85965250

Nickel, tube, 100mm, outside diameter 3.0mm, inside diameter 2.4mm, wall thickness 0.3mm, hard, 99.5%

GF90932823

Nickel, rod, 100mm, diameter 6.35mm, 99%

GF50593002

Nickel, rod, 100mm, diameter 9.5mm, 99%

GF17365192

Nickel, foil, 1m coil, thickness 0.1mm, annealed, 99%

GF11598194

Nickel, rod, 100mm, diameter 12.7mm, 99.98%

GF07926037

Nickel, rod, 50mm, diameter 40mm, 99%

GF84148397

Nickel, foil, 1m coil, thickness 0.075mm, annealed, 99%

GF12735783

Nickel, rod, 500mm, diameter 6.35mm, 99%

GF71201168

Nickel, sphere, 100pcs, diameter 0.76mm, precision sphere grade 200, 99%

GF61643842

Nickel, sphere, 100pcs, diameter 3.0mm, precision sphere grade 200, 99%

GF44869731

Nickel, wire reel, 20m, diameter 0.025mm, as drawn, 99.98%

GF60907091

Nickel, wire reel, 20m, diameter 1.0mm, hard, 99.98%

GF66482040

Nickel, wire reel, 20m, diameter 0.05mm, as drawn, 99%

GF43517976

Nickel, wire reel, 20m, diameter 2.0mm, hard, 99.98%

GF99749648

Nickel, wire reel, 20m, diameter 0.125mm, annealed, 99.98%

266981

Sigma-Aldrich

Nickel, powder, <50 μm, 99.7% trace metals basis

GF03846102

Nickel, foil, 25x25mm, thickness 0.5mm, annealed, 99.98%

GF07087439

Nickel, tube, 500mm, outside diameter 3.0mm, inside diameter 2.4mm, wall thickness 0.3mm, hard, 99.5%

GF19263405

Nickel, rod, 1000mm, diameter 12.7mm, 99.98%

GF98554078

Nickel, tube, 500mm, outside diameter 3.25mm, inside diameter 3.05mm, wall thickness 0.1mm, hard, 99.5%

GF60655967

Nickel, pellets, 50g, max. size 10mm, 99.99+%