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Merck

25170

Sigma-Aldrich

1-(氯甲基)萘

technical, ≥97.0% (GC)

别名:

1-萘甲基氯

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About This Item

线性分子式:
C10H7CH2Cl
CAS号:
分子量:
176.64
Beilstein:
636885
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

等級

technical

化驗

≥97.0% (GC)

形狀

solid

顏色

deep brown

折射率

n20/D 1.635 (lit.)
n20/D 1.635

bp

167-169 °C/25 mmHg (lit.)

mp

32 °C (lit.)

密度

1.18 g/mL at 25 °C (lit.)

SMILES 字串

ClCc1cccc2ccccc12

InChI

1S/C11H9Cl/c12-8-10-6-3-5-9-4-1-2-7-11(9)10/h1-7H,8H2

InChI 密鑰

XMWGTKZEDLCVIG-UHFFFAOYSA-N

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一般說明

Kinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated.

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

269.6 °F - closed cup

閃點(°C)

132 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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其他客户在看

Formation kinetics and spectra of aromatic radicals in solution.
Kelley DF, et al.
The Journal of Physical Chemistry, 87(11), 1842-1843 (1983)
Bo Peng et al.
Organic letters, 13(19), 5402-5405 (2011-09-14)
Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives to produce ortho- or para-substituted carbocycles in satisfactory to excellent yields has been developed. The unprecedented dearomatization reactions proceeded smoothly under mild conditions via η(3)-benzylpalladium intermediates.

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