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Merck

106631

Sigma-Aldrich

对甲基苯甲酰氯

98%

别名:

4-甲基苯甲酰氯

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About This Item

线性分子式:
CH3C6H4COCl
CAS号:
分子量:
154.59
Beilstein:
471492
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

5.33 (vs air)

蒸汽壓力

0.55 mmHg ( 20 °C)

化驗

98%

expl. lim.

1.6 %, 117 °F

折射率

n20/D 1.553 (lit.)

bp

225-227 °C (lit.)
95-96 °C/10 mmHg (lit.)

mp

−4-−2 °C (lit.)

密度

1.169 g/mL at 25 °C (lit.)

SMILES 字串

Cc1ccc(cc1)C(Cl)=O

InChI

1S/C8H7ClO/c1-6-2-4-7(5-3-6)8(9)10/h2-5H,1H3

InChI 密鑰

NQUVCRCCRXRJCK-UHFFFAOYSA-N

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一般說明

p -甲苯甲酰氯使用三氟乙酸官能化介孔 Zr-TMS 催化剂使甲苯发生苯甲酰化反应 。使用受阻格氏试剂 2,6-二甲基苯基溴化镁 ,可导致双吡咯甲烷 1,9-二酰基化。

應用

用 p -甲苯甲酰氯制备抗原,甲苯酰-酰胺-人血清白蛋白

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

179.6 °F - closed cup

閃點(°C)

82 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Landge SM, et al.
J. Mol. Catal. A: Chem., 213(2), 257-266 (2004)
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Journal of chromatography. A, 1476, 53-62 (2016-11-20)
In order to comprehensively understand the influence of coordination of the substituent at 2-position with those at 3- and 6-positions on the properties of chitosan derivatives, a series of chitosan 3,6-bis(arylcarbamate)-2-(amide)s (CACAs) and the related chiral stationary phases (CSPs) were
M H Karol et al.
Clinical allergy, 10(1), 101-109 (1980-01-01)
Two antigens, both containing tolyl groups, were compared for ability to detect IgE antibodies in workers hypersensitive to toluene diisocyanate. One antigen, formed by reaction of p-tolyl isocyanate with human serum albumin, detected antibodies in each of ten hypersensitive workers.
Komal M Vyas et al.
Chemico-biological interactions, 240, 250-266 (2015-09-06)
Pyrazolone based metal complexes have strong bio-activity but the anti-cancer mechanism of these derivatives is not fully understood. In recent years, Cu(II) complexes have attracted the interest of researchers increasingly because of their high antitumor activities that are usually related
Nearly Chromatography-Free Synthesis of the A3B-Porphyrin 5-(4-Hydroxymethylphenyl)-10, 15, 20-tri-p-tolylporphinatozinc (II).
Zaidi SHH, et al.
Organic Process Research & Development, 10(2), 304-314 (2006)

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