902144

[(Cp)Ru(η⁶-naphthalene)]OTf

≥95%

• Synonyme(s) : (η⁵-Cyclopentadienyl)(η⁶-naphthalene)ruthenium(1+) trifluoromethanesulfonate
• Formule empirique (notation de Hill): C₁₆H₁₃F₃O₃RuS
• Numéro CAS: 811794-35-1
• Poids moléculaire : 443.40
• Code UNSPSC : 12352101

Propriétés

• Pureté: ≥95%
• Forme: powder
• Pertinence de la réaction: reagent type: catalyst; reaction type: C-C Bond Formation
• Pf: 112-116 °C
• Température de stockage: 2-8°C

Description

Application

Stable precursor for synthesis and ruthenium catalysis. It was also used by the Ritter lab to synthesize an Fmoc-protected ruthenium tyrosine for subsequent incorporation of the [18F]fluoride radiolabel into polypeptides.

Autres remarques

Site-Specific Deoxyfluorination of Small Peptides with [18F]Fluoride

Comparison of the Catalytic Activity of [(5-C5H5)Ru(2,2′-bipyridine)(L)]OTf versus [(5-C5H5)Ru(6,6′-diamino-2,2′-bipyridine)(L)]OTf (L = labile ligand) in the Hydrogenation of Cyclohexanone. Evidence for the Presence of a Metal–Ligand Bifunctional Mechanism under Acidic Conditions

Arene Exchange in the Ruthenium-Naphthalene Complex [CpRu(C10H8)]+

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable