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Sigma-Aldrich

Bis(cyclopentadienyl)ruthenium(II)

97%

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About This Item

Empirical Formula (Hill Notation):
C10H10Ru
CAS Number:
1287-13-4
Molecular Weight:
231.26
EC Number:
215-065-2
MDL number:
MFCD00001442
UNSPSC Code:
12352103
PubChem Substance ID:
24855742
NACRES:
NA.23

Assay

97%

form

solid

reaction suitability

core: ruthenium
reagent type: catalyst

mp

199-201 °C (lit.)

SMILES string

[Ru].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.Ru/c2*1-2-4-5-3-1;/h2*1-5H;

InChI key

BKEJVRMLCVMJLG-UHFFFAOYSA-N

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Pricing

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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M Wenzel et al.
International journal of radiation applications and instrumentation. Part A, Applied radiation and isotopes, 38(1), 67-69 (1987-01-01)
The radioactive decay of [103Ru]ruthenocene derivatives leads to 103mRh labelled rhodocinium derivatives, which can be separated by the extraction of a lipophilic solution of the ruthenocen derivate with water. The separation factor 103mRh/103Ru reaches values of 32:1 Rh3+ ions are
M Schneider et al.
Zeitschrift fur Naturforschung. Section C, Biosciences, 37(1-2), 136-138 (1982-01-01)
In buffer solution (pH 7,4) ruthenocene and osmocene are far more stable than ferrocene. The metallocenes ruthenocene and osmocene are metabolized by microsomes of mouse liver in the presence of NADPH and O2. The Km-values are similar for both metallocenes
Adam J Salmon et al.
Chemical communications (Cambridge, England), 48(17), 2328-2330 (2012-01-20)
We have determined the protein X-ray crystal structures of four organometallic inhibitors in complex with their target enzyme carbonic anhydrase II. The barrel-shaped hydrophobic ferrocene and ruthenocene moieties have provided a structure-based avenue to better occupy the hydrophobic binding patch
Cynthia T Sanderson et al.
Inorganic chemistry, 44(9), 3283-3289 (2005-04-26)
Electronic absorption and resonance Raman spectral studies of benzoylruthenocene (BRc) and 1,1'-dibenzoylruthenocene (DRc) indicate that the low-energy electronic excited states of these 4d(6) metallocenes possess metal-to-ligand charge transfer (MLCT) character. While this MLCT contribution should weaken the metal-ring bonding in
Malay Patra et al.
Chemical communications (Cambridge, England), 47(41), 11444-11446 (2011-09-22)
A convenient synthesis of azidomethyl-ruthenocene and its use in the covalent labelling of amino acids, peptides and a peptide nucleic acid (PNA) monomer derivative by Cu(I) catalyzed azide-alkyne coupling (Cu-AAC, "click chemistry") are described.
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