Carbohydrate-Catalyzed Enantioselective Alkene Diboration: Enhanced Reactivity of 1,2-Bonded Diboron Complexes.

Carbohydrate-Catalyzed Enantioselective Alkene Diboration: Enhanced Reactivity of 1,2-Bonded Diboron Complexes.

Journal of the American Chemical Society (2016-02-09)

Lichao Fang, Lu Yan, Fredrik Haeffner, James P Morken

RESUMEN

Catalytic enantioselective diboration of alkenes is accomplished with readily available carbohydrate-derived catalysts. Mechanistic experiments suggest the intermediacy of 1,2-bonded diboronates.

MATERIALES

Referencia del producto

Marca

Descripción del producto

901235

Sigma-Aldrich

TBS-DHG Catalyst, ≥95%