520160

Shi Epoxidation Diketal Catalyst

98%

• Sinónimos: 1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose
• Fórmula empírica (notación de Hill): C₁₂H₁₈O₆
• Número de CAS: 18422-53-2
• Peso molecular: 258.27
• Número MDL: MFCD11865369
• Código UNSPSC: 12352005
• ID de la sustancia en PubChem: 24874093
• NACRES: NA.22

Propiedades

• Análisis: 98%
• actividad óptica: [α]20/D −120.9°, c = 1 in chloroform
• características de los productos alternativos más sostenibles: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 102-104 °C (lit.)
• categoría alternativa más sostenible: , Aligned
• cadena SMILES: CC1(C)O[C@@H]2CO[C@]3(COC(C)(C)O3)C(=O)[C@@H]2O1
• InChI: 1S/C12H18O6/c1-10(2)15-6-12(18-10)9(13)8-7(5-14-12)16-11(3,4)17-8/h7-8H,5-6H2,1-4H3/t7-,8-,12+/m1/s1
• Clave InChI: IVWWFWFVSWOTLP-RWYTXXIDSA-N

Descripción

Descripción general

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Aplicación

Highly selective and active organocatalyst for the asymmetric epoxidation of alkenes with hydrogen peroxide. Green epoxidation catalyst of choice according to Glaxo-Smith-Kline's reagent guide.

An Efficient Catalytic Asymmetric Epoxidation Method

Use of an Iridium-Catalyzed Redox-Neutral Alcohol-Amine Coupling on Kilogram Scale for the Synthesis of a GlyT1 Inhibitor

This organocatalyst is able to epoxidize trans alkenes and certain cis alkenes with good to excellent yields and selectivities.

Información de seguridad

• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable
• Equipo de protección personal: Eyeshields, Gloves, type N95 (US)