237116

Bis(triphenylphosphine)nickel(II) dichloride

synthesis grade

• Synonym(s): NiCl₂(PPh₃)₂, Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride
• Linear Formula: [(C₆H₅)₃P]₂NiCl₂
• CAS Number: 14264-16-5
• Molecular Weight: 654.17
• EC Number: 238-154-8
• MDL number: MFCD00009592
• UNSPSC Code: 12161600
• PubChem Substance ID: 24854218
• NACRES: NA.22

Properties

• grade: synthesis grade
• form: solid
• reaction suitability: core: nickel; reagent type: catalyst
• mp: 250 °C (dec.) (lit.)
• SMILES string: Cl[Ni]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
• InChI: 1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
• InChI key: ZBRJXVVKPBZPAN-UHFFFAOYSA-L

Description

Application

Catalyst in the coupling reaction of aryl mesylates and allylic carbonates with lithium organoborates.

Safety Information

• Pictograms: GHS08,GHS07
• Signal Word: Danger
• Hazard Statements: H317,H350,H412
• Precautionary Statements: P202 - P261 - P273 - P280 - P302 + P352 - P308 + P313
• Hazard Classifications: Aquatic Chronic 3 - Carc. 1B - Skin Sens. 1
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves