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Sigma-Aldrich

Di(1-adamantyl)-n-butylphosphine hydriodide

95%

Synonym(s):

Di(1-adamantanyl)-n-butyl-phosphonium iodide, cataCXium® AHI

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About This Item

Empirical Formula (Hill Notation):
C24H40IP
CAS Number:
714951-87-8
Molecular Weight:
486.45
MDL number:
MFCD10566973
UNSPSC Code:
12352001
PubChem Substance ID:
329760432
NACRES:
NA.22

Assay

95%

form

solid

reaction suitability

reaction type: Asymmetric synthesis
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

functional group

phosphine

SMILES string

I.CCCCP([C@]12C[C@H]3C[C@H](C[C@H](C3)C1)C2)[C@@]45C[C@@H]6C[C@@H](C[C@@H](C6)C4)C5

InChI

1S/C24H39P.HI/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;/h17-22H,2-16H2,1H3;1H/t17-,18+,19-,20-,21+,22-,23-,24-;

InChI key

IBXHWLZKSOGUFS-HDWJELNESA-N

Related Categories

General description

sold in collaboration with Solvias AG

Application

Phosphonium salts are ligand precursors for the palladium-catalyzed amination, and Suzuki coupling

Legal Information

US7148176
cataCXium is a registered trademark of Umicore AG & Co. KG

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Articles

cataCXium®

cataCXium® - Ligands and Complexes for Efficient Cross-Coupling Reactions. Cross-coupling reactions are an important class of catalytic transformations with applications in polymer science as well as in the fine chemicals and pharmaceutical industries.

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