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  • As(III) removal by palladium-modified nitrogen-doped titanium oxide nanoparticle photocatalyst.

As(III) removal by palladium-modified nitrogen-doped titanium oxide nanoparticle photocatalyst.

Environmental science & technology (2009-04-09)
Qi Li, Nickolas Joseph Easter, Jian Ku Shang
ABSTRACT

Removal of arsenic species from water by palladium-modified nitrogen-doped titanium oxide (TiON/PdO) nanoparticles was investigated with and without visible light. For the first time, a high degree of As(III) removal undervisible light illumination was demonstrated on oxide photocatalysts. Over 2 orders of magnitude decrease of As(III) concentration in waterwas observed in 1 h as the As(III) concentration was reduced below the U.S. Environmental Protection Agency standard (10 microg/L) by TiON/PdO photocatalyst Such an efficient removal of As(III) was shown to result from the combined effects of strong adsorption and photooxidation by TiON/PdO, where an enhanced photocatalytic activity undervisible light illumination than nitrogen-doped titanium oxide (TiON) was derived from the strong optoelectronic coupling between PdO and TiON.

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Palladium(II) oxide, 99.97% trace metals basis
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