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71742

Sigma-Aldrich

Sodium methanethiolate

technical, ≥90% (RT)

Synonym(s):

Methanethiol sodium salt, Sodium thiomethoxide

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About This Item

Linear Formula:
CH3SNa
CAS Number:
5188-07-8
Molecular Weight:
70.09
Beilstein:
3592983
EC Number:
225-969-9
MDL number:
MFCD00174316
UNSPSC Code:
12352100
PubChem Substance ID:
57652357
NACRES:
NA.22

grade

technical

Quality Level

200

Assay

≥90% (RT)

form

solid

SMILES string

[Na+].C[S-]

InChI

1S/CH4S.Na/c1-2;/h2H,1H3;/q;+1/p-1

InChI key

RMBAVIFYHOYIFM-UHFFFAOYSA-M

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Other Notes

Strong nucleophile used for the synthesis of methyl aryl sulfides from halo-arenes; Alkanethiolates are efficient reagents for SN2 dealkylation of esters and aryl ethers

Signal Word

Danger

Hazard Statements

H228,H301,H314

Hazard Classifications

Acute Tox. 3 Oral - Flam. Sol. 1 - Skin Corr. 1A

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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T.R. Kelly et al.
Tetrahedron Letters, 3859-3859 (1977)
D. Chianelli et al.
Synthesis, 475-475 (1982)
P. Cogolli et al.
The Journal of Organic Chemistry, 44, 2642-2642 (1979)
L. Testaferri et al.
Synthesis, 751-751 (1983)
Nikolaos Kontoudakis et al.
Food research international (Ottawa, Ont.), 98, 95-102 (2017-06-15)
A variety of techniques have been developed with the ability to measure different forms of metals in wine with the ultimate aim of providing a more accurate indicator of metal induced spoilage of wine. This study was conducted in order
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