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  • Novel bisimidazolium pincers as low loading ligands for in situ palladium-catalyzed Suzuki-Miyaura reaction in the ambient atmosphere.

Novel bisimidazolium pincers as low loading ligands for in situ palladium-catalyzed Suzuki-Miyaura reaction in the ambient atmosphere.

Chemical communications (Cambridge, England) (2013-01-04)
Chao Gao, Hongjun Zhou, Siping Wei, Yinsong Zhao, Jingsong You, Ge Gao
ZUSAMMENFASSUNG

A series of novel triazinonide-bridged bisimidazolium pincers were easily synthesized by quaternization of functionalized N-phenylimidazoles with highly reactive cyanuric chloride under mild conditions. The pincer was proven to be a very efficient ligand for in situ Pd-catalyzed Suzuki-Miyaura reaction with ppm-level catalyst loading.

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Marke
Produktbeschreibung

Sigma-Aldrich
Cyanurchlorid, 99%