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Oleanane-type isomeric triterpenoids from Barringtonia racemosa.

Journal of natural products (2009-04-25)
P Mangala Gowri, S V S Radhakrishnan, S Jeelani Basha, A V S Sarma, J Madhusudana Rao
ZUSAMMENFASSUNG

Two new isomeric acylated oleanane-type triterpenoids along with three known compounds were isolated from the MeOH extract of the dried fruits of Barringtonia racemosa. On the basis of spectroscopic methods, with special emphasis on 1D and 2D NMR techniques as well as chemical methods, the structures were characterized as racemosol A (1) [22alpha-acetoxy-3beta,15alpha,16alpha,21beta-tetrahydroxy-28-(2-methylbutyryl)olean-12-ene] and isoracemosol A (2) [21beta-acetoxy-3beta,15alpha,16alpha,28-tetrahydroxy-22alpha-(2-methylbutyryl)olean-12-ene]. The isolated compounds (1-5) were not active against HeLa and P388 D1 carcinoma cell lines.

MATERIALIEN
Produktnummer
Marke
Produktbeschreibung

Sigma-Aldrich
Stigmasterol, ~95%
Supelco
Stigmasterol, certified reference material, 10 mg/mL in chloroform