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Merck

711268

Sigma-Aldrich

N-tert-Butyl-O-[1-[4-(Chlormethyl)phenyl]ethyl]-N-(2-Methyl-1-phenylpropyl)hydroxylamin

Synonym(e):

Alkoxyamin NMP Initiator

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About This Item

Empirische Formel (Hill-System):
C23H32ClNO
CAS-Nummer:
Molekulargewicht:
373.96
MDL-Nummer:
UNSPSC-Code:
12162002
PubChem Substanz-ID:
NACRES:
NA.23

Form

solid

mp (Schmelzpunkt)

43-47 °C

Lagertemp.

−20°C

SMILES String

CC(C)C(N(OC(C)c1ccc(CCl)cc1)C(C)(C)C)c2ccccc2

InChI

1S/C23H32ClNO/c1-17(2)22(21-10-8-7-9-11-21)25(23(4,5)6)26-18(3)20-14-12-19(16-24)13-15-20/h7-15,17-18,22H,16H2,1-6H3

InChIKey

WZYBDTCNEIULNZ-UHFFFAOYSA-N

Allgemeine Beschreibung

For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.

Piktogramme

Flame over circleCorrosion

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Ox. Sol. 3 - Skin Corr. 1B

Lagerklassenschlüssel

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flammpunkt (°F)

>230.0 °F - closed cup

Flammpunkt (°C)

> 110 °C - closed cup


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Artikel

A detailed article on block copolymer synthesis using a nitroxide-mediated radical polymerization (NMP) approach.

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.

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Protokolle

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

An article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

Unser Team von Wissenschaftlern verfügt über Erfahrung in allen Forschungsbereichen einschließlich Life Science, Materialwissenschaften, chemischer Synthese, Chromatographie, Analytik und vielen mehr..

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