377481

Isopropyltriphenylphosphoniumiodid

98%

• Synonym(e): (1-Methylethyl)triphenylphosphonium iodide, NSC 140615
• Lineare Formel: (CH₃)₂CHP(C₆H₅)₃I
• CAS-Nummer: 24470-78-8
• Molekulargewicht: 432.28
• EG-Nummer: 246-281-5
• MDL-Nummer: MFCD00031595
• UNSPSC-Code: 12352002
• PubChem Substanz-ID: 24863508
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 98%
• Form: solid
• Eignung der Reaktion: reaction type: C-C Bond Formation
• mp (Schmelzpunkt): 194-197 °C (lit.)
• Funktionelle Gruppe: phosphine
• SMILES String: [I-].CC(C)[P+](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C21H22P.HI/c1-18(2)22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-18H,1-2H3;1H/q+1;/p-1
• InChIKey: HHBXWXJLQYJJBW-UHFFFAOYSA-M

Beschreibung

Anwendung

Employed in Wittig and cyclopropanation reactions.

Reactant for:

• Total synthesis of heliananes
• Preparation of highly substituted benzene derivatives
• Synthesis of curcuphenol and elvirol analogs via a retro-aldol reaction as fungicidal agents
• 4-substituted methoxylbenzoyl-aryl-thiazoles analogues as potent and orally bioavailable anticancer agents
• Wittig reaction

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves