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Sigma-Aldrich

Thiomorpholin

98%

Synonym(e):

Tetrahydro-2H-1,4-thiazin, Thiamorpholin

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About This Item

Empirische Formel (Hill-System):
C4H9NS
CAS-Nummer:
123-90-0
Molekulargewicht:
103.19
Beilstein:
102550
EG-Nummer:
204-660-2
MDL-Nummer:
MFCD00005974
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24851748
NACRES:
NA.22

Assay

98%

Brechungsindex

n20/D 1.538 (lit.)

bp

169 °C (lit.)

Löslichkeit

organic solvents: miscible(lit.)
water: miscible(lit.)

Dichte

1.026 g/mL at 25 °C (lit.)

SMILES String

C1CSCCN1

InChI

1S/C4H9NS/c1-3-6-4-2-5-1/h5H,1-4H2

InChIKey

BRNULMACUQOKMR-UHFFFAOYSA-N

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Allgemeine Beschreibung

Thiomorpholine forms complexes with Cu(II), Pt(II) and Ni(II) salts and their catalytic activity has been investigated.

Anwendung

Thiomorpholine has been used in the preparation of:
  • N-Boc-α-alkyl-β-(sec-amino)alanines
  • thiomorpholine-N-borane

Piktogramme

Corrosion
GHS05

Signalwort

Danger

H-Sätze

H314

Gefahreneinstufungen

Eye Dam. 1 - Skin Corr. 1B

Lagerklassenschlüssel

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flammpunkt (°F)

145.4 °F - closed cup

Flammpunkt (°C)

63 °C - closed cup

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Analysenzertifikate (COA)

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Sigma-Aldrich

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Sigma-Aldrich

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Mesut Kacan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 118, 572-577 (2013-10-05)
Several Cu(II), Pt(II) and Ni(II) complexes of N-substituted, piperazine (NN donor), morpholine (NO donor) and thiomorpholine (NS donor) derivatives were synthesized and their thermal behavior and catalytic activity in epoxidation reaction of cis-diphenylethylene were studied using oxygen sources NaOCl. The
Synthesis and comparative reactivity of thiomorpholine-borane: aqueous hydrolysis and oxidation by hypochlorite.
Amezcua CA, et al.
Inorgorganica Chimica Acta, 290(1), 80-85 (1999)
N Someswara Rao et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(12), 2737-2757 (2002-10-25)
The natural abundance 15N-NMR chemical shifts of selected aliphatic amines, 2-substituted pyridine type compounds, bialicyclic tertiary amines have been measured as a function of the nature of the solvent. In the case of cyclic aliphatic amines, like piperidine, morpholine, piperazine
Amany Belal
Bioorganic chemistry, 59, 124-129 (2015-03-10)
A new series of pyrrolizine derivatives 4-8c were synthesized, their structures were confirmed by spectral and elemental analyses. Cytotoxic activity of these compounds was evaluated against breast (MCF7), colon (HCT116) and liver (HEPG2) cancer cell lines using sulphorhodamine-B (SRB) assay
Saurav Bera et al.
ACS combinatorial science, 14(1), 1-4 (2011-12-01)
Diastereoselective trans-2,5-disubstituted amino acids derived diverse morpholines, piperazines and thiomorpholines were prepared in 30 min-1 h with high yields through iodine-mediated 6-exotrig type cyclization from a single common synthetic intermediate. The displacement of iodine with hydride ion gave a methyl
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