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Key Documents

199966

Sigma-Aldrich

Aluminum oxide

activated, acidic, Brockmann I

Sinonimo/i:

Alumina

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About This Item

Formula condensata:
Al2O3
Numero CAS:
Peso molecolare:
101.96
Numero CE:
Numero MDL:
Codice UNSPSC:
12352311
eCl@ss:
38120402
ID PubChem:
NACRES:
SB.52

Grado

Brockmann I
activated
standard grade

agenzia

suitable for EPA 1613

Forma fisica

powder

Produttore/marchio commerciale

CAMAG 504-C-I

tecniche

ion chromatography: suitable

Impurezze

<0.03% Fe2O3
<0.03% SiO2
<0.4% Na2O

Dimensione particelle

50-300 mesh

Dimensione pori

58 Å pore size

pH

4.5±0.5 ( in H2O)

Punto di fusione

2040 °C (lit.)

Anioni in tracce

chloride (Cl-): ≤0.14 (mval/g)

Stringa SMILE

O=[Al]O[Al]=O

InChI

1S/2Al.3O
TWNQGVIAIRXVLR-UHFFFAOYSA-N

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Descrizione generale

Brockmann aluminum oxides are suitable for column chromatography and adsorptive filtration.
The mechanism of formation of protective scales of α-Al2O3 (aluminum oxide) on surfaces of binary M-Al (M = Fe, Ni or Co) alloys at high temperatures has been studied. Activated aluminum oxides having different acidities and water concentrations (having Brockmann activity I-V) can easily detect various types of water (namely free water, pore water, and bound water) on the aluminum oxide present in soils.

Applicazioni

Aluminum oxide (Alumina) may be used for the removal of peroxides from the dehydration solvent (tetrahydrofuran, THF) in a protocol. Protocol involved the high resolution study of fine brain anatomy of fluorescently labeled mouse brains. It may be used in the fabrication of polycrystalline lithium iodide-Aluminum oxide solid electrolytes. The incorporation of aluminum oxide remarkably increased the conductivity of lithium iodide.
Aluminum oxide (acidic) can be used as an adsorbent for column chromatography. It may be used as an active surface for the acylation of aromatic ethers with carboxylic acids in the presence of trifluoroacetic anhydride under solvent-free conditions.

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

nwg

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


Certificati d'analisi (COA)

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A simple, efficient, and selective method for tetrahydropyranylation of alcohols on a solid phase of alumina impregnated with zinc chloride.
Ranu BC and Saha M.
The Journal of Organic Chemistry, 59(26), 8269-8270 (1994)
Efficient Syntheses of (a-Fluoropropargyl) phosphonate Esters.
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Micron-scale resolution optical tomography of entire mouse brains with confocal light sheet microscopy.
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Journal of Visualized Experiments, 80, e50696-e50696 (2013)
Conduction Characteristics of the Lithium Iodide-Aluminum Oxide Solid Electrolytes.
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Thermoanalytical studies of water on activated alumina, Brockmann I-V,(acid, neutral, basic) from- 60? to+ 700? C.
Hampson JW and Bleam WF.
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