A24109
Acryloyl chloride
≥97%, contains ~400 ppm phenothiazine as stabilizer
Sinonimo/i:
Acrylic acid chloride, prop-2-enoyl chloride, 2-Propenoyl chloride
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About This Item
Formula condensata:
CH2=CHCOCl
Numero CAS:
Peso molecolare:
90.51
Beilstein:
635744
Numero CE:
Numero MDL:
Codice UNSPSC:
12162002
ID PubChem:
NACRES:
NA.23
Prodotti consigliati
Densità del vapore
>1 (vs air)
Livello qualitativo
Tensione di vapore
1.93 psi ( 20 °C)
Saggio
≥97%
Forma fisica
liquid
contiene
~400 ppm phenothiazine as stabilizer
Indice di rifrazione
n20/D 1.435 (lit.)
P. eboll.
72-76 °C (lit.)
Densità
1.114 g/mL at 25 °C (lit.)
Temperatura di conservazione
2-8°C
Stringa SMILE
ClC(=O)C=C
InChI
1S/C3H3ClO/c1-2-3(4)5/h2H,1H2
HFBMWMNUJJDEQZ-UHFFFAOYSA-N
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Categorie correlate
Descrizione generale
Acryloyl chloride, an organic chemical compound, serves primarily as a reactive monomer for synthesizing polymers and copolymers applicable in diverse fields like adhesives, coatings, hydrogel coatings, sustained drug release, hydrogel film, organic electronic devices and plastics. Phenothiazine is commonly used as a stabilizer for acryloyl chloride during polymerization. It is added in small quantities (400ppm), to prevent the formation of unwanted by-products and to extend the shelf life of the reactive monomer. It also acts as a scavenger for free radicals that may form during the polymerization process.
Applicazioni
Acryloyl chloride can be used as:
- A monomer to synthesize crosslinked zwitterionic hydrogel coatings for sensing and detection in complex media.
- A reactant to synthesize crosslinked hydrogel film by reacting with a hydrophilic monomer called N,N-(dimethylacrylamide) (DMAA). The prepared hydrogel film is further used in sustained drug delivery.
- A monomer in the preparation of acrylate-based polymers with excellent n-type semiconducting properties, which are important for the development of organic electronic devices.
- The cyclam monomer. The polymer of this modified cyclam monomer can be used in specific transition metal binding.
Avvertenze
Danger
Indicazioni di pericolo
Classi di pericolo
Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1A
Rischi supp
Codice della classe di stoccaggio
3 - Flammable liquids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
30.2 °F
Punto d’infiammabilità (°C)
-1 °C
Certificati d'analisi (COA)
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I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.
Iris Ben-David et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 58(2), 209-217 (2003-02-08)
An automated procedure for the radiosynthesis of the labeling synthon [11C]acryloyl chloride was developed and applied for labeling several N-acryl amides with carbon-11. [11C]-6-acrylamido-4-(3,4-dichloro-6-fluoroanilino)quinazoline (ML03), a novel PET biomarker targeting the epidermal growth factor receptor tyrosine kinase (EGFr-TK) in cancer
V Fulcrand et al.
International journal of peptide and protein research, 38(3), 273-277 (1991-09-01)
Copolymers of acrylated derivatives of alpha-chymotrypsin and polyethylene glycol (PEG) have been prepared and used as biocatalysts for the synthesis of model peptides in organic solvent containing a low quantity of water. Other peptide couplings have been tried to point
J C Tiller et al.
Proceedings of the National Academy of Sciences of the United States of America, 98(11), 5981-5985 (2001-05-17)
Poly(4-vinyl-N-alkylpyridinium bromide) was covalently attached to glass slides to create a surface that kills airborne bacteria on contact. The antibacterial properties were assessed by spraying aqueous suspensions of bacterial cells on the surface, followed by air drying and counting the
Combined CASSCF and MR-CI study on photoinduced dissociation and isomerization of acryloyl chloride.
Gang-Long Cui et al.
The journal of physical chemistry. A, 110(42), 11839-11846 (2006-10-20)
The potential energy surfaces of isomerization and dissociation reactions for CH2CHCOCl in the S0, T1, T2, and S1 states have been mapped with DFT, CASSCF, MP2, and MR-CI calculations. Rate constants for adiabatic and nonadiabatic processes have been calculated with
R Bahulekar et al.
Biomaterials, 20(4), 357-362 (1999-02-27)
Poly(N-alkyl mono and disubstituted) acrylamide derivatives were synthesized from poly(acryloyl chloride) by monomer analogous reaction. The polymers were characterized by FTIR-ATR and GPC. The contact angle measurements were performed to evaluate hydrophobic/hydrophilic characters of these polymers. The N-alkyl substituents changed
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