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Sigma-Aldrich

Iron(III) chloride solution

greener alternative

0.2 M in 2-methyltetrahydrofuran

Sinonimo/i:

Ferric chloride solution

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About This Item

Formula condensata:
FeCl3
Numero CAS:
7705-08-0
Peso molecolare:
162.20
Numero MDL:
MFCD00011005
Codice UNSPSC:
12352300
ID PubChem:
329763016
NACRES:
NA.22

Forma fisica

solution

Livello qualitativo

100

Impiego in reazioni chimiche

core: iron
reagent type: catalyst

Caratteristiche più verdi

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Catalysis
Learn more about the Principles of Green Chemistry.

Concentrazione

0.2 M in 2-methyltetrahydrofuran

Indice di rifrazione

n20/D 1.414

Densità

0.868 g/mL at 25 °C

Categoria alternativa più verde

, Aligned

Stringa SMILE

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
RBTARNINKXHZNM-UHFFFAOYSA-K

Categorie correlate

Descrizione generale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. FeCl3 is used in many biomass conversion processes because of its unique properties such as nontoxicity, low-cost, abundance, and high selectivity. Here, this product is 0.2 M in 2-methyltetrahydrofuran and thus aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks", and has been enhanced for catalytic efficiency. Click here for more information.

Applicazioni

Iron(III) chloride in greener solvent, 2-methyltetrahydrofuran (2-MeTHF) can be used:
  • As a mild oxidant for phenolic coupling reaction.
  • In dimerizing aryllithiumsand ketone enolates.
  • As a mild Lewis acid catalyst to catalyzes ene reactions.
  • In Nazarov cyclizations, Michael additions, and acetonation reactions.


2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Avvertenze

Danger

Indicazioni di pericolo

H225 - H290 - H302 - H315 - H318

Classi di pericolo

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2

Rischi supp

EUH019

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

14.0 °F - closed cup

Punto d’infiammabilità (°C)

-10.0 °C - closed cup

Certificati d'analisi (COA)

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Abdelwareth A O Sarhan et al.
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access
Chen-Yu Chen et al.
Clinica chimica acta; international journal of clinical chemistry, 438, 337-341 (2014-10-05)
Insulin-like growth factor binding protein-1 (IGFBP-1) constitutes a subgroup of the insulin-like growth factor binding protein systems, and its concentration in amniotic fluid is 100-1000 times higher than the concentration in other body fluids. The aim of this study was
William H DePas et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(7), 2629-2634 (2013-01-30)
Bacterial biofilm formation is a complex developmental process involving cellular differentiation and the formation of intricate 3D structures. Here we demonstrate that exposure to ferric chloride triggers rugose biofilm formation by the uropathogenic Escherichia coli strain UTI89 and by enteric
D C Florian Wieland et al.
Colloids and surfaces. B, Biointerfaces, 109, 74-81 (2013-04-27)
The early stages of the formation of inorganic aggregates, composed of iron compounds at the solution-air interface, were investigated in situ. The properties of the solution-air interface were changed by using different Langmuir layers. In order to get insight into
Dattatraya H Dethe et al.
Organic letters, 15(3), 429-431 (2013-01-16)
A novel approach was developed for the synthesis of highly substituted indene derivatives, using an FeCl(3) catalyzed Prins-type cyclization reaction which was further applied in the total synthesis of jungianol and epi-jungianol.
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