563722

3-Chlorophenylmagnesium bromide

0.5 M in THF

• Sinonimo/i: (3-Chlorophenyl)magnesium bromide, (m-Chlorophenyl)magnesium bromide, 3-chloro phenyl magnesium bromide, 3-chlorophenyl magnesium bromide, m-chlorophenyl magnesium bromide, Bromo(3-chlorophenyl)magnesium
• Formula empirica (notazione di Hill): C₆H₄BrClMg
• Numero CAS: 36229-42-2
• Peso molecolare: 215.76
• Numero MDL: MFCD00672003
• Codice UNSPSC: 12352103
• ID PubChem: 24880124
• NACRES: NA.22

Proprietà

• Impiego in reazioni chimiche: reaction type: Grignard Reaction
• Concentrazione: 0.5 M in THF
• P. eboll.: 65 °C (lit.)
• Densità: 0.960 g/mL at 25 °C (lit.)
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: Clc1cccc([Mg]Br)c1
• InChI: 1S/C6H4Cl.BrH.Mg/c7-6-4-2-1-3-5-6;;/h1-2,4-5H;1H;/q;;+1/p-1; ZIYRUWPTUPFRQU-UHFFFAOYSA-M

Descrizione

Applicazioni

3-Chlorophenylmagnesium bromide (o-chlorophnylmagnesium bromide) is a Grignard reagent that can be used to synthesize:

• 2,3-Di(o-chlorophenyl)buta-1,3-dienes by reacting with 1,4-dimethoxy 2-butyne in the presence of a copper(I) salt.
• 2-Bromo-5-chlorothiophen-3-yl-(3-chlorophenyl)methanol by reacting with 2-bromo-5-chlorothiophene-3-carbaldehyde.
• 2-(3-Chlorophenyl)-1-phenyl-1H-inden-1-ol from 2- benzoylbenzonitrile as a starting a material.

Note legali

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Informazioni sulla sicurezza

• Pittogrammi: GHS02,GHS08,GHS07
• Avvertenze: Danger
• Indicazioni di pericolo: H225,H302,H319,H335,H351
• Consigli di prudenza: P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Classi di pericolo: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• Organi bersaglio: Respiratory system
• Rischi supp: EUH019
• Codice della classe di stoccaggio: 3 - Flammable liquids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): <1.4 °F - closed cup
• Punto d’infiammabilità (°C): < -17 °C - closed cup