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463779

Sigma-Aldrich

Ruthenium(III) chloride hydrate

99.98% trace metals basis

Sinonimo/i:

Trichlororuthenium hydrate, Ruthenium trichloride

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About This Item

Formula condensata:
RuCl3 · xH2O
Numero CAS:
14898-67-0
Peso molecolare:
207.43 (anhydrous basis)
Numero CE:
233-167-5
Numero MDL:
MFCD00149844
Codice UNSPSC:
12352302
ID PubChem:
24870096
NACRES:
NA.23

Livello qualitativo

100

Saggio

99.98% trace metals basis

Forma fisica

powder and chunks

Impiego in reazioni chimiche

reagent type: catalyst
core: ruthenium

Impurezze

≤250.0 ppm Trace Metal Analysis

Stringa SMILE

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3
BIXNGBXQRRXPLM-UHFFFAOYSA-K

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Categorie correlate

Descrizione generale

Ruthenium(III) chloride hydrate exhibits excellent catalytic activity, attributed to the redox properties of ruthenium suitable for fuel cells and other electrochemical devices. It has ability to facilitate charge transfer and exhibit photoactive behavior.

Applicazioni

Ruthenium(III) chloride hydrate can be used:
  • As a precursor to prepare ultralow Ru loaded graphene aerogel that exhibits electrocatalytic performance in the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR).
  • As a dopant to prepare Ru-doped TiO2 electron transport layer for mesoscopic perovskite solar cell by spin-coating technique. This helps to enhance photoconversion efficiency and air stability.
  • To fabricate ultra-uniform Ru nanocluster catalyst via small-molecule self-assembly pyrolysis method. These catalysts exhibit excellent hydrogen evolution activity in Zinc air batteries under all pH conditions.

Altre note

soluble form

Avvertenze

Danger

Indicazioni di pericolo

H302,H314,H411

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Codice della classe di stoccaggio

8A - Combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificati d'analisi (COA)

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Fujita, S.-I., et al.
J. Catal., 255, 95-95 (2004)
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
Cho, C.S. et al.
Tetrahedron Letters, 40, 1499-1499 (1999)
Yao Zhang et al.
European journal of medicinal chemistry, 86, 449-455 (2014-09-10)
Ruthenium-based anticancer complexes have become increasingly popular for study over the last two decades. Although ruthenium complexes are currently being investigated in clinical trials, there are still some difficulties with their delivery and associated side effects. Human serum albumin (HSA)-based
Huaiyi Huang et al.
Dalton transactions (Cambridge, England : 2003), 44(35), 15602-15610 (2015-08-08)
Ruthenium complexes have been considered as promising substitutes for cisplatin in cancer chemotherapy. However, novel ruthenium-based therapies are faced with some limitations, such as unimpressive cytotoxicity toward solid tumors. Herein, we designed and synthesized phenyl-substituted terpyridyl ruthenium(ii) complexes ([Ru(tpy)(bpy)Cl](+) (Ru1)
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