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208302

Sigma-Aldrich

Lead(II) thiocyanate

99.5% trace metals basis

Sinonimo/i:

Lead sulfocyanide, Lead(II) rhodanide, Plumbous thiocyanate

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About This Item

Formula condensata:
Pb(SCN)2
Numero CAS:
592-87-0
Peso molecolare:
323.36
Beilstein:
3687984
Numero CE:
209-774-6
Numero MDL:
MFCD00011155
Codice UNSPSC:
12352100
ID PubChem:
24852505
NACRES:
NA.22

Saggio

99.5% trace metals basis

Forma fisica

powder

Punto di fusione

190 °C (dec.) (lit.)

Solubilità

cold water: soluble 200 part(lit.)
water: soluble 50 part (boiling)(lit.)

Densità

3.82 g/mL at 25 °C (lit.)

Stringa SMILE

N#CS[PbH2]SC#N

InChI

1S/2CHNS.Pb/c2*2-1-3;/h2*3H;/q;;+2/p-2
VRNINGUKUJWZTH-UHFFFAOYSA-L

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Applicazioni

Lead (II) thiocyanate can be used:
  • To form a complex with Schiff-base lariat crown ether, N,N′-bis(3-(salicylaldimino)benzyl)-4,13-diaza-18-crown-6.
  • To investigate complexing and fluorescence properties of calixarene bearing two dansyl fluorophores grafted on a large pore mesoporous silica material.
  • As a reagent in the 1,2-dithiocyanation of alkynes in the presence of (dichloroiodo)benzene.
  • As a precursor to synthesize perovskite films for solar cell applications.

Avvertenze

Danger

Classi di pericolo

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1A - STOT RE 2

Codice della classe di stoccaggio

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Certificati d'analisi (COA)

Cerca il Certificati d'analisi (COA) digitando il numero di lotto/batch corrispondente. I numeri di lotto o di batch sono stampati sull'etichetta dei prodotti dopo la parola ‘Lotto’ o ‘Batch’.

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A mesoporous silica functionalized by a covalently bound calixarene-based fluoroionophore for selective optical sensing of mercury (II) in water
M'etivier R, et al.
Journal of Materials Chemistry, 15(27-28), 2965-2973 (2005)
(Dichloroiodo) benzene and lead (II) thiocyanate as an efficient reagent combination for stereoselective 1, 2-dithiocyanation of alkynes
Prakash O, et al.
Tetrahedron Letters, 42(4), 553-555 (2001)
O Prakash et al.
The Journal of organic chemistry, 66(6), 2019-2023 (2001-04-13)
The combination reagent (dichloroiodo)benzene and lead(II) thiocyanate in dichloromethane effects oxidation of various enol silyl ethers, ketene silyl acetals, and beta-dicarbonyl compounds, thereby providing an efficient and convenient method for alpha-thiocyanation of carbonyl and beta-dicarbonyl compounds.
Lewis-base adducts of lead (II) compounds. XX. Synthesis and structure of the 1: 1 adduct of pyridine with lead (II) thiocyanate.
Harrowfield JM, et al.
Australian Journal of Chemistry, 49(10), 1165-1169 (1996)
A mesoporous silica functionalized by a covalently bound calixarene-based fluoroionophore for selective optical sensing of mercury (II) in water.
Metivier R, et al.
Journal of Materials Chemistry, 15(27-28), 2695-2673 (2005)
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