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Merck

A catalyst for efficient and highly enantioselective hydrogenation of aromatic, heteroaromatic, and alpha,beta-unsaturated ketones

Organic letters (2001-01-11)
Burk, Hems, Herzberg, Malan, Zanotti-Gerosa
RÉSUMÉ

PhanePhos-ruthenium-diamine complexes catalyze the asymmetric hydrogenation of a wide range of aromatic, heteroaromatic, and alpha, beta-unsaturated ketones with high activity and excellent enantioselectivity.

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Sigma-Aldrich
(R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, 96%
Sigma-Aldrich
(S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, 96%