479500

1,2-Bis(dicyclohexylphosphino)ethane

• Synonyme(s) : Ethylenebis(dicyclohexylphosphine), 1,2-Ethanediylbis[dicyclohexyl]phosphine
• Formule linéaire : (C₆H₁₁)₂PCH₂CH₂P(C₆H₁₁)₂
• Numéro CAS: 23743-26-2
• Poids moléculaire : 422.61
• Numéro MDL: MFCD00015521
• Code UNSPSC : 12352001
• ID de substance PubChem : 24871622
• Nomenclature NACRES : NA.22

Propriétés

• Forme: solid
• Pertinence de la réaction: reagent type: ligand; reaction type: Decarboxylations; reagent type: ligand; reaction type: Negishi Coupling; reagent type: ligand; reaction type: Suzuki-Miyaura Coupling
• Pf: 92.5-96.5 °C (lit.)
• Groupe fonctionnel: phosphine
• Chaîne SMILES: C1CCC(CC1)P(CCP(C2CCCCC2)C3CCCCC3)C4CCCCC4
• InChI: 1S/C26H48P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h23-26H,1-22H2
• Clé InChI: BOUYBUIVMHNXQB-UHFFFAOYSA-N

Description

Application

1,2-Bis(dicyclohexylphosphino)ethane can be used as a ligand for:

• Pd-catalyzed decarbonylative C-H coupling of azoles and aromatic esters.
• Ni-catalyzed cross-coupling reaction of aryl fluorides and primary amines.

Reactant involved in:

• Investigations of the role of ligand-based steric effects during the polymerization
• Synthesis of molybdenum nitrosyl complexes for use as Imine hydrogenation catalysts
• Irreversible thermal linkage isomerization of switchable C-N-bound isomers
• Chelating for conversion of trans complexes to cis complexes

Precursor for Iridium trisboryl complexes and the substituent effect on borylation reactions

Ligand for palladium(II) complex catalyzed hydrogenation reactions

Informations sur la sécurité

• Pictogrammes: GHS05,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H315,H318,H335,H413
• Conseils de prudence: P261 - P264 - P273 - P280 - P302 + P352 - P305 + P351 + P338
• Classification des risques: Aquatic Chronic 4 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): >230.0 °F - closed cup
• Point d'éclair (°C): > 110 °C - closed cup
• Équipement de protection individuelle: Eyeshields, Gloves, type N95 (US)