374377

2-(Triphenylphosphoranylidene)propionaldehyde

98%

• Synonyme(s) : 1-Formylethylidenetriphenylphosphorane
• Formule linéaire : (C₆H₅)₃P=C(CH₃)CHO
• Numéro CAS: 24720-64-7
• Poids moléculaire : 318.35
• Numéro MDL: MFCD00075596
• Code UNSPSC : 12352114
• ID de substance PubChem : 24863304
• Nomenclature NACRES : NA.22

Propriétés

• Pureté: 98%
• Forme: powder
• Capacité de réaction: reaction type: C-C Bond Formation
• Pf: 219-221 °C (lit.)
• Chaîne SMILES: CC(C=O)=P(c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C21H19OP/c1-18(17-22)23(19-11-5-2-6-12-19,20-13-7-3-8-14-20)21-15-9-4-10-16-21/h2-17H,1H3
• Clé InChI: VHUQEFAWBCDBSC-UHFFFAOYSA-N

Description

Application

Reactant for:

• Preparation of acitretin analogs with antitumor activity
• Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration
• Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination
• Wittig reactions
• Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents
• Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors of IMPDH

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Gloves, type N95 (US)