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  • Development of highly active and selective novel Pd based acetoxylation catalysts and prevention of catalyst deactivation by Bi modification.

Development of highly active and selective novel Pd based acetoxylation catalysts and prevention of catalyst deactivation by Bi modification.

Chemical communications (Cambridge, England) (2004-10-30)
A Benhmid, K V Narayana, A Martin, B Lucke, M-M Pohl
ABSTRACT

A first approach to successful prevention of catalyst deactivation while simultaneously achieving extremely high selectivity of benzyl acetate (> or = 95%) at significantly high toluene conversion (> 70%) by gas phase acetoxylation over novel Pd-Sb-Bi/TiO2 catalysts.

MATERIALS
Product Number
Brand
Product Description

Supelco
Benzyl acetate, analytical standard
Sigma-Aldrich
Benzyl acetate, ≥99%, FCC, FG
Sigma-Aldrich
Benzyl acetate, natural, ≥99%, FCC, FG
Sigma-Aldrich
Benzyl acetate, ≥99%