46318
Sulcotrione
PESTANAL®, analytical standard
Synonym(s):
2-[2-Chloro-4-(methylsulfonyl)benzoyl]-1,3-cyclohexanedione
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About This Item
Empirical Formula (Hill Notation):
C14H13ClO5S
CAS Number:
Molecular Weight:
328.77
Beilstein:
8155739
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24
grade
analytical standard
Quality Level
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable
gas chromatography (GC): suitable
application(s)
agriculture
environmental
format
neat
SMILES string
CS(=O)(=O)c1ccc(c(Cl)c1)C(=O)C2C(=O)CCCC2=O
InChI
1S/C14H13ClO5S/c1-21(19,20)8-5-6-9(10(15)7-8)14(18)13-11(16)3-2-4-12(13)17/h5-7,13H,2-4H2,1H3
InChI key
PQTBTIFWAXVEPB-UHFFFAOYSA-N
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General description
Sulcotrione is a herbicide belonging to the triketone class, commonly used in corn production.
Application
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Sulcotrione may be used as an analytical reference standard for the quantification of the analyte in environmental samples using liquid chromatography coupled to tandem mass spectrometry.
Recommended products
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - Skin Sens. 1A - STOT RE 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Boris Eyheraguibel et al.
Journal of agricultural and food chemistry, 59(9), 4868-4873 (2011-03-24)
Pesticide reactivity toward light is rarely considered at the leaf surface after crop treatment; regardless, these degradation reactions directly impact the pesticide effectiveness. The use of sunscreen adjuvants to overcome photodegradation has presented some limitations so far. Raw hydroalcoholic plant
Luciana Gomides Freitas et al.
Journal of chromatography. A, 1028(2), 277-286 (2004-03-03)
The LC/ESI/MSMS method allows the trace quantification (ng/l) of the new triketone herbicides, i.e. sulcotrione and mesotrione, and important herbicides and metabolites, in natural waters. Solid phase extraction (SPE) for sample enrichment is performed with OASIS (recoveries 94-112% for parent
P D Fraser et al.
The Plant journal : for cell and molecular biology, 24(4), 551-558 (2000-12-15)
The application of high-performance liquid chromatography (HPLC) using a C30 reverse-phase stationary matrix has enabled the simultaneous separation of carotenes, xanthophylls, ubiquinones, tocopherols and plastoquinones in a single chromatogram. Continuous photodiode array (PDA) detection ensured identification and quantification of compounds
Minir Murati et al.
Environmental science and pollution research international, 19(5), 1563-1573 (2011-11-26)
The degradation and mineralization of two triketone (TRK) herbicides, including sulcotrione and mesotrione, by the electro-Fenton process (electro-Fenton using Pt anode (EF-Pt), electro-Fenton with BDD anode (EF-BDD) and anodic oxidation with BDD anode) were investigated in acidic aqueous medium. The
Richard Cherrier et al.
Pest management science, 61(9), 899-904 (2005-07-26)
A soil column experiment under outdoor conditions was performed to monitor the fate of 14C-ring-labelled sulcotrione, 2-(2-chloro-4-mesylbenzoyl)cyclohexane-1,3-dione and atrazine, 6-chloro-N2-ethyl-N4-isopropyl-1,3,5-triazine-2,4-diamine, in water leachates and in the ploughed horizon of a sandy loam soil. Two months after treatment, the cumulative amounts
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